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Author(s):   Haszeldine, R.N.; Parkinson, C.; Robinson, P.J.; Williams, W.J.
Title:   Carbene chemistry. Part 12. Kinetics of the isomerisation, addition, and insertion reacitons of 1,2,2-trifluoroethylidene
Journal:   J. Chem. Soc. Perkin Trans. 2
Page(s):   954 - 961
Year:   1979
Reference type:   Journal article
Squib:   1979HAS/PAR954-961

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1979HAS/PAR954-961   iso-C4H10 + CHF2CF: → Adduct  444 - 462   2.06E-35       -3.18E04      2
  Reference reaction:  CHF2CF: → C2HF3 1
  1979HAS/PAR954-961   CH3CH=CH2 + CHF2CF: → Adduct  438 - 462   4.15E-10       4.90E04      2
  1979HAS/PAR954-961   CH3CH=CH2 + CHF2CF: → Adduct  438 - 462   1.45E-35       -4.61E04      2
  Reference reaction:  CHF2CF: → C2HF3 1
  1979HAS/PAR954-961   C2HF3 + CHF2CF: → Adduct  432 - 462   2.16E-29       2.04E04      2
  Reference reaction:  CHF2CF: → C2HF3 1
  1979HAS/PAR954-961   (Z)-2-C4H8 + CHF2CF: → Adduct  591 - 623   4.17E-10       5.00E04      2
  1979HAS/PAR954-961   (Z)-2-C4H8 + CHF2CF: → Adduct  591 - 623   9.96E-36       -4.89E04      2
  Reference reaction:  CHF2CF: → C2HF3 1
  1979HAS/PAR954-961   (CH3)3SiH + CHF2CF: → (CH3)3SiCHFCHF2  440 - 462   4.17E-10       4.70E04      2
  1979HAS/PAR954-961   (CH3)3SiH + CHF2CF: → (CH3)3SiCHFCHF2  442 - 462   6.99E-37       -6.04E04      2
  Reference reaction:  CHF2CF: → C2HF3 1
  1979HAS/PAR954-961   CHF2CF: → C2HF3  440 - 623   2.51E13       9.56E04      1

Search returned 9 records.