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Accessibility information
Author(s):   Quick, L.M.; Whittle, E.
Title:   Reactions of Trifluoromethyl radicals with organic halides. Part 6.-Bromo- and fluoro-bromoethanes
Journal:   Trans. Faraday Soc.
Volume:   67
Year:   1971
Reference type:   Journal article
Squib:   1971QUI/WHI1727

Reaction:   CH2BrCH2Br + ·CF3CF3Br + CH3CHBr
Reaction order:   2
Reference reaction:   ·CF3 + ·CF3C2F6
Temperature:   297 - 493 K
Pressure:  3.60E-2 - 5.33E-2 bar
Rate expression:   1.99x10-13 [cm3/molecule s] e-32343 [±8314472 J/mole]/RT
Uncertainty:   1.39999998
Bath gas:   (CF3)2CO
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
297 4.09E-19
300 4.66E-19
325 1.26E-18
350 2.97E-18
375 6.23E-18
400 1.19E-17
425 2.11E-17
450 3.51E-17
475 5.53E-17
493 7.46E-17