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Author(s):   Tsang, W.
Title:   Chemical kinetic data base for combustion chemistry. Part 4. Isobutane
Journal:   J. Phys. Chem. Ref. Data
Volume:   19
Page(s):   1 - 68
Year:   1990
Reference type:   Journal article
Squib:   1990TSA1-68

Reaction:   C2H4 + tert-C4H9Isobutene + ·C2H5
Reaction order:   2
Reference reaction:   C2H4 + tert-C4H9(CH3)2C=CHCH3 + ·CH3
Reference reaction order:   2
Temperature:   300 - 2500 K
Rate expression:   5.0x10-1 e9977 [J/mole]/RT
Uncertainty:   1.5
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
300 2.73E1
400 1.00E1
500 5.51E0
600 3.69E0
700 2.78E0
800 2.24E0
900 1.90E0
1000 1.66E0
1100 1.49E0
1200 1.36E0
1300 1.26E0
1400 1.18E0
1500 1.11E0
1600 1.06E0
1700 1.01E0
1800 9.74E-1
1900 9.40E-1
2000 9.11E-1
2100 8.85E-1
2200 8.63E-1
2300 8.42E-1
2400 8.24E-1
2500 8.08E-1