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Accessibility information
Author(s):   Faravelli, T.; Goldaniga, A.; Zappella, L.; Ranzi, E.; Dagaut, P.; Cathonnet, M.
Title:   An experimental and kinetic modeling study of propyne and allene oxidation
Journal:   Proc. Combust. Inst.
Volume:   28
Page(s):   2601 - 2608
Year:   2000
Reference type:   Journal article
Squib:   2000FAR/GOL2601-2608

Reaction:   CH3COCO + ·CH3
Reaction order:   1
Temperature:   800 - 1200 K
Pressure:  1.01 - 10.13 bar
Rate expression:   2.5x1012 [s-1] e-60250 [J/mole]/RT
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   Rate constant is high pressure limit
Experimental procedure:   Stirred flow reactor(PSR etc.)
Time resolution:   In real time
Analytical technique:   GC-MS

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
800 2.91E8
825 3.83E8
850 4.96E8
875 6.33E8
900 7.97E8
925 9.90E8
950 1.22E9
975 1.48E9
1000 1.78E9
1025 2.13E9
1050 2.52E9
1075 2.95E9
1100 3.44E9
1125 3.99E9
1150 4.59E9
1175 5.24E9
1200 5.96E9