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Accessibility information
Author(s):   Arican, M.H.; Potter, E.; Whytock, D.A.
Title:   Reactions of trifluoromethyl radicals with propane, n-butane and isobutane
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   69
Page(s):  
Year:   1973
Reference type:   Journal article
Squib:   1973ARI/POT1811

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1973ARI/POT1811   C3H8 + ·CF3 → Other Products + CHF3  318 - 505   6.31E-13       2.89E04      2
  1973ARI/POT1811   C3H8 + ·CF3CHF3 + 2-C3H7  318 - 505   3.02E-13       2.73E04      2
  1973ARI/POT1811   C3H8 + ·CF3CHF3 + 2-C3H7  318 - 505   0.34       -8564      2
  Reference reaction:  C3H8 + ·CF3CHF3 + 1-C3H7 2
  1973ARI/POT1811   C3H8 + ·CF3CHF3 + 1-C3H7  318 - 505   8.92E-13       3.58E04      2
  1973ARI/POT1811   iso-C4H10 + ·CF3 → Other Products + CHF3  315 - 405   1.91E-13       2120      2
  1973ARI/POT1811   iso-C4H10 + ·CF3CHF3 + tert-C4H9  315 - 405   1.32E-13       2.03E04      2
  1973ARI/POT1811   iso-C4H10 + ·CF3CHF3 + tert-C4H9  315 - 405   0.04       -1.84E04      2
  Reference reaction:  iso-C4H10 + ·CF3CHF3 + iso-C4H9 2
  1973ARI/POT1811   iso-C4H10 + ·CF3CHF3 + iso-C4H9  315 - 485   3.09E-12       3.87E04      2
  1973ARI/POT1811   1-C4H10 + ·CF3 → Other Products + CHF3  314 - 443   2.96E-13       2.40E04      2
  1973ARI/POT1811   1-C4H10 + ·CF3CHF3 + sec-C4H9  314 - 443   2.24E-13       2.34E04      2
  1973ARI/POT1811   1-C4H10 + ·CF3CHF3 + sec-C4H9  314 - 443   0.41       -1.11E04      2
  Reference reaction:  1-C4H10 + ·CF3CHF3 + 1-C4H9 2
  1973ARI/POT1811   1-C4H10 + ·CF3CHF3 + 1-C4H9  314 - 443   6.46E-13       3.44E04      2

Search returned 12 records.