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Author(s):   Alarcon, P.; Bohn, B.; Zetzsch, C.; Rayez, M. T.; Rayez, J. C.
Title:   Reversible addition of the OH radical to p-cymene in the gas phase: multiple adduct formation. Part 2
Journal:   Phys. Chem. Chem. Phys.
Volume:   16
Page(s):   17315 - 17326
Year:   2014
Reference type:   Journal article
Squib:   2014ALA/BOH17315-17326

Reaction:   p-Cimene + ·OH4-Methylphenol + 2-C3H7
Reaction order:   2
Temperature:   298 K
Pressure:  0.76 bar
Rate expression:   6.18x10-18 [cm3/molecule s]
Category:  Experiment
Data type:   Transition state theory
Pressure dependence:   Rate constant is pressure dependent
Comments:   Reaction potential energy surface was studied using quantum chemistry and rate constants were calculated using transition state theory and RRKM. Rate constant for 400 K is also presented in Table 4 of the article.

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