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Author(s):   Arican, M.H.; Potter, E.; Whytock, D.A.
Title:   Reactions of trifluoromethyl radicals with propane, n-butane and isobutane
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   69
Page(s):  
Year:   1973
Reference type:   Journal article
Squib:   1973ARI/POT1811

Reaction:   iso-C4H10 + ·CF3CHF3 + tert-C4H9
Reaction order:   2
Temperature:   315 - 405 K
Pressure:  3.71E-2 - 7.20E-2 bar
Rate expression:   1.32x10-13 [cm3/molecule s] e-20287 [J/mole]/RT
Bath gas:   CF3I
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
315 5.70E-17
325 7.24E-17
350 1.24E-16
375 1.97E-16
400 2.96E-16
405 3.19E-16