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Title: Reactions of trifluoromethyl radicals with propane, n-butane and isobutane
Journal: J. Chem. Soc. Faraday Trans. 1
Volume: 69
Page(s):
Year: 1973
Reference type: Journal article
Squib: 1973ARI/POT1811
Reaction:
iso-C4H10 + ·CF3 → CHF3 + tert-C4H9
Reaction order:
2
Temperature:
315 - 405
K
Pressure: 3.71E-2 - 7.20E-2 bar
Rate expression:
1.32x10-13 [cm3/molecule s] e-20287 [J/mole]/RT
Bath gas:
CF3I
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 315 | 5.70E-17 |
| 325 | 7.24E-17 |
| 350 | 1.24E-16 |
| 375 | 1.97E-16 |
| 400 | 2.96E-16 |
| 405 | 3.19E-16 |