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Author(s):   Clarke, J.S.; Donahue, N.M.; Kroll, J.H.; Rypkema, H.A.; Anderson, J.G.
Title:   An Experimental Method for Testing Reactivity Models: A High-Pressure Discharge-Flow Study of H + Alkene and Haloalkene Reactions
Journal:   J. Phys. Chem. A
Volume:   104
Page(s):   5254 - 5264
Year:   2000
Reference type:   Journal article
Squib:   2000CLA/DON5254-5264

Reaction:   (E)-2-C4H8 + → Products
Reaction order:   2
Temperature:   298 - 370 K
Pressure:  6.67E-2 bar
Rate expression:   6.31x10-11 [±6.14x10-12 cm3/molecule s] e-10726 [±249 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Discharge
Time resolution:   In real time
Analytical technique:   Resonance fluorescence
Comments:   Authors did not provide fits of the temperature dependence in the standard Arrhenius form. The listed values were calculated at NIST from the data in Table 2 of the paper.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 8.32E-13
300 8.56E-13
325 1.19E-12
350 1.58E-12
370 1.93E-12