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Author(s):   Tahan, A.; Shiroudi, A.
Title:   Oxidation reaction mechanism and kinetics between OH radicals and alkyl-substituted aliphatic thiols: OH-addition pathways
Journal:   Prog. React. Kinet. Mech.
Volume:   44
Page(s):   157 - 174
Year:   2019
Reference type:   Journal article
Squib:   2019TAH/SHI157-174

Reaction:   C2H5SH + ·OHH2O + CH3CH2S
Reaction order:   2
Temperature:   252 - 425 K
Pressure:  1.00E-8 - 1.00E8 bar
Rate expression:   no rate data available
Category:  Theory
Data type:   Transition state theory
Pressure dependence:   Rate constant is pressure dependent
Comments:   Reaction potential energy surface was studied using quantum chemistry and reaction channels were analyzed. Rate constants were calculated over ranges of temperatures and pressures using transition state theory and RRKM. No Arrhenius expressions are given. Rate constants are presented in tabular and graphical formats.

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