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Author(s):   Shaw, J.T.; Lidster, R.T.; Cryer, D.R.; Ramirez, N.; Whiting, F.C.; Boustead, G.A.; Whalley, L.K.; Ingham, T.; Rickard, A.R.; Dunmore, R.E.; Heard, D.E.; Lewis, A.C.; Carpenter, L.J.; Hamilton, J.F.; Dillon, T.J.
Title:   A self-consistent, multivariate method for the determination of gas-phase rate coefficients, applied to reactions of atmospheric VOCs and the hydroxyl radical
Journal:   Atmos. Chem. Phys.
Volume:   18
Page(s):   4039 - 4054
Year:   2018
Reference type:   Journal article
Squib:   2018SHA/LID4039-4054

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2018SHA/LID4039-4054   ·OH + β-Ocimene → Products  295   2.23E-10              2
  2018SHA/LID4039-4054   γ-Terpinene + ·OH → Products  295   2.07E-10              2
  2018SHA/LID4039-4054   Myrcene + ·OH → Products  295   2.04E-10              2
  2018SHA/LID4039-4054   Limonene + ·OH → Products  295   1.52E-10              2
  2018SHA/LID4039-4054   CH2=C(CH3)CH=CH2 + ·OH → Products  295   1.04E-10              2
  2018SHA/LID4039-4054   ·OH + 3-Carene → Products  295   9.70E-11              2
  2018SHA/LID4039-4054   beta-pinene + ·OH → Products  295   7.80E-11              2
  2018SHA/LID4039-4054   alpha-pinene + ·OH → Products  295   5.60E-11              2
  2018SHA/LID4039-4054   1,3-Dimethylbenzene + ·OH → Products  295   2.20E-11              2
  2018SHA/LID4039-4054   1,2-Dimethylbenzene + ·OH → Products  295   4.80E-12              2
  2018SHA/LID4039-4054   CH2=C(CH3)CH=CH2 + ·OH → Products  295   1.03E-10              2
  2018SHA/LID4039-4054   beta-pinene + ·OH → Products  295   7.50E-11              2
  2018SHA/LID4039-4054   (Z)-Cycloheptene + ·OH → Products  295   7.40E-11              2
  2018SHA/LID4039-4054   Cyclohexene + ·OH → Products  295   7.10E-11              2
  2018SHA/LID4039-4054   Cyclopentene + ·OH → Products  295   6.90E-11              2
  2018SHA/LID4039-4054   ·OH + C2H5CH(CH3)C(CH3)=CH2 → Products  295   5.70E-11              2
  2018SHA/LID4039-4054   alpha-pinene + ·OH → Products  295   5.30E-11              2
  2018SHA/LID4039-4054   1-C8H16 + ·OH → Products  295   4.40E-11              2
  2018SHA/LID4039-4054   1-C9H18 + ·OH → Products  295   4.10E-11              2
  2018SHA/LID4039-4054   1-C7H14 + ·OH → Products  295   3.60E-11              2
  2018SHA/LID4039-4054   1-C6H12 + ·OH → Products  295   4.60E-11              2
  2018SHA/LID4039-4054   ·OH + β-Ocimene → Products  323   9.50E-10              2
  2018SHA/LID4039-4054   Myrcene + ·OH → Products  323   3.10E-10              2
  2018SHA/LID4039-4054   α-Terpinene + ·OH → Products  323   1.80E-10              2
  2018SHA/LID4039-4054   Limonene + ·OH → Products  323   1.40E-10              2
  2018SHA/LID4039-4054   ·OH + 3-Carene → Products  323   8.10E-11              2
  2018SHA/LID4039-4054   beta-pinene + ·OH → Products  323   8.10E-11              2
  2018SHA/LID4039-4054   CH2=C(CH3)CH=CH2 + ·OH → Products  323   7.50E-11              2
  2018SHA/LID4039-4054   alpha-pinene + ·OH → Products  323   5.00E-11              2
  2018SHA/LID4039-4054   Camphene + ·OH → Products  323   5.00E-11              2
  2018SHA/LID4039-4054   (Z)-Cycloheptene + ·OH → Products  323   7.10E-11              2
  2018SHA/LID4039-4054   Cyclopentene + ·OH → Products  323   5.80E-11              2
  2018SHA/LID4039-4054   Cyclohexene + ·OH → Products  323   5.70E-11              2
  2018SHA/LID4039-4054   1-C6H12 + ·OH → Products  323   3.10E-11              2
  2018SHA/LID4039-4054   1-C7H14 + ·OH → Products  323   1.80E-11              2
  2018SHA/LID4039-4054   Cyclooctane + ·OH → Products  323   1.74E-11              2
  2018SHA/LID4039-4054   Cycloheptane + ·OH → Products  323   1.50E-11              2
  2018SHA/LID4039-4054   Ethylcyclohexane + ·OH → Products  323   1.50E-11              2
  2018SHA/LID4039-4054   3-Methylheptane + ·OH → Products  323   1.40E-11              2
  2018SHA/LID4039-4054   1-C10H22 + ·OH → Products  323   1.40E-11              2
  2018SHA/LID4039-4054   n-C9H20 + ·OH → Products  323   1.40E-11              2
  2018SHA/LID4039-4054   2-Methylheptane + ·OH → Products  323   1.22E-11              2
  2018SHA/LID4039-4054   (CH3)2CH(CH2)2CH3 + ·OH → Products  323   1.20E-11              2
  2018SHA/LID4039-4054   (C2H5)2CHCH3 + ·OH → Products  323   9.10E-12              2
  2018SHA/LID4039-4054   n-C8H18 + ·OH → Products  323   8.80E-12              2
  2018SHA/LID4039-4054   1-C7H16 + ·OH → Products  323   7.90E-12              2
  2018SHA/LID4039-4054   2,2,3-Trimethylbutane + ·OH → Products  323   6.30E-12              2
  2018SHA/LID4039-4054   1-Ethyl-3-methylbenzene + ·OH → Products  323   3.40E-11              2
  2018SHA/LID4039-4054   1,2,4-Trimethylbenzene + ·OH → Products  323   3.20E-11              2
  2018SHA/LID4039-4054   1,2,3-Trimethylbenzene + ·OH → Products  323   3.10E-11              2
  2018SHA/LID4039-4054   Naphthalene + ·OH → Products  323   2.20E-11              2
  2018SHA/LID4039-4054   1,3-Dimethylbenzene + ·OH → Products  323   2.10E-11              2
  2018SHA/LID4039-4054   2,3-Dihydroindene + ·OH → Products  323   1.90E-11              2
  2018SHA/LID4039-4054   1-Ethyl-4-methylbenzene + ·OH → Products  323   1.56E-11              2
  2018SHA/LID4039-4054   1-Ethyl-2-methylbenzene + ·OH → Products  323   1.50E-11              2
  2018SHA/LID4039-4054   1,2-Dimethylbenzene + ·OH → Products  323   1.30E-11              2
  2018SHA/LID4039-4054   p-Cimene + ·OH → Products  323   1.20E-11              2
  2018SHA/LID4039-4054   1-Phenylpropane + ·OH → Products  323   8.50E-12              2
  2018SHA/LID4039-4054   2-Phenylpropane + ·OH → Products  323   7.20E-12              2
  2018SHA/LID4039-4054   Ethylbenzene + ·OH → Products  323   7.00E-12              2
  2018SHA/LID4039-4054   Toluene + ·OH → Products  323   5.10E-12              2

Search returned 61 records.