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Author(s):   Becerra, R.; Boganov, S.E.; Egorov, M.P.; Faustov, V.I.; Krylova, I.V.; Nefedov, O.M.; Walsh, R.
Title:   First Gas-Phase Detection of Dimethylstannylene and Time-Resolved Study of Some of Its Reactions
Journal:   J. Am. Chem. Soc.
Volume:   124
Page(s):   7555 - 7562
Year:   2002
Reference type:   Journal article
Squib:   2002BEC/BOG7555-7562

Reaction:   (CH3)4Sn + CH3Sn(·)CH3 → Products
Reaction order:   2
Temperature:   296 K
Pressure:  6.67E-3 - 1.33E-2 bar
Rate expression:   3.0x10-11 [cm3/molecule s]
Rate constant is an upper limit.
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Vis-UV absorption
Comments:   Reported uncertainties are one sigma and are precision only.

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