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Author(s):   Tedder, J.M.; Walton, J.C.; Winton, K.D.R.
Title:   Free radical addition to olefins. Part 8. Addition of n-heptafluoropropyl radicals to fluoro-ethylenes
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   68
Page(s):   160 - 166
Year:   1972
Reference type:   Journal article
Squib:   1972TED/WAL160-166

Reaction:   CH2=CF2 + CF3CF2CF2I → CF3CF2CF2CF2CH2I
Reaction order:   2
Reference reaction:   C2H4 + CF3CF2CF2I → n-C3F7CH2CH2I
Reference reaction order:   2
Temperature:   341 - 477 K
Pressure:  6.13E-2 bar
Rate expression:   2.2x10-1 e-11141 [±1231 J/mole]/RT
Uncertainty:   1.04999995
Bath gas:   CF3CF2CF2I
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
341 4.32E-3
350 4.78E-3
375 6.17E-3
400 7.72E-3
425 9.40E-3
450 1.12E-2
475 1.31E-2
477 1.33E-2