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Author(s):   Alwe, H.D.; Walawalkar, M.; Sharma, A.; Pushpa, K.K.; Dhanya, S.; Naik, P.D.
Title:   Rate Coefficients for the Gas-Phase Reactions of Chlorine Atoms with Cyclic Ethers at 298 K
Journal:   Int. J. Chem. Kinet.
Volume:   45
Page(s):   295 - 305
Year:   2013
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2013ALW/WAL295-305

Reaction:   Tetrahydro-2H-pyran + ·Cl → Products
Reaction order:   2
Reference reaction:   1-C6H14 + ·Cl → Products
Reference reaction order:   2
Temperature:   298 K
Pressure:  1.07 bar
Rate expression:   8.2x10-1±3.0x10-2
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   The errors quoted for relative rate ratios are 2σ of the statistical variation in different sets of experiments.

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