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Author(s):   Alwe, H.D.; Walawalkar, M.; Sharma, A.; Pushpa, K.K.; Dhanya, S.; Naik, P.D.
Title:   Rate Coefficients for the Gas-Phase Reactions of Chlorine Atoms with Cyclic Ethers at 298 K
Journal:   Int. J. Chem. Kinet.
Volume:   45
Page(s):   295 - 305
Year:   2013
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2013ALW/WAL295-305

Reaction:   Tetrahydro-2H-pyran + ·Cl → Products
Reference reaction:   1-C6H14 + ·Cl → Products
Temperature:   298 K
Pressure:  1.07 bar
Rate expression:   2.52x10-10±3.6x10-11
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   This value obtained in nitrogen gas is recommended by the authors. The errors obtained for relative rate ratios are 2σ of the statistical variation in different sets of experiments. These errors, combined with the reported errors of the reference rate coefficients using the statistical error propagation equation, are the quoted errors for the rate coefficients.

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