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Author(s):   Brown, T.C.; King, K.D.
Title:   Very low-pressure pyrolysis (VLPP) of methyl- and ethynyl- cyclopentanes and cyclohexanes
Journal:   Int. J. Chem. Kinet.
Volume:   21
Page(s):   251 - 266
Year:   1989
Reference type:   Journal article
Squib:   1989BRO/KIN251-266

Reaction:   Methylcyclopentane → Other Products + C2H5CH2C(CH3)=CH2
Reaction order:   1
Temperature:   1020 - 1220 K
Rate expression:   3.98x1016 [s-1] e-353365 [±10559 J/mole]/RT
Uncertainty:   2.0
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1020 3.19E-2
1025 3.91E-2
1050 1.05E-1
1075 2.69E-1
1100 6.61E-1
1125 1.56E0
1150 3.55E0
1175 7.79E0
1200 1.65E1
1220 2.96E1