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Title: Very low-pressure pyrolysis (VLPP) of methyl- and ethynyl- cyclopentanes and cyclohexanes
Journal: Int. J. Chem. Kinet.
Volume: 21
Page(s): 251 - 266
Year: 1989
Reference type: Journal article
Squib: 1989BRO/KIN251-266
Reaction:
Methylcyclopentane → Other Products + C2H5CH2C(CH3)=CH2
Reaction order:
1
Temperature:
1020 - 1220
K
Rate expression:
3.98x1016 [s-1] e-353365 [±10559 J/mole]/RT
Uncertainty:
2.0
Category: Experiment
Data type:
High or low pressure extrapolation
Excitation technique:
Thermal
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 1020 | 3.19E-2 |
| 1025 | 3.91E-2 |
| 1050 | 1.05E-1 |
| 1075 | 2.69E-1 |
| 1100 | 6.61E-1 |
| 1125 | 1.56E0 |
| 1150 | 3.55E0 |
| 1175 | 7.79E0 |
| 1200 | 1.65E1 |
| 1220 | 2.96E1 |