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Accessibility information
Author(s):   Bacskay, G.B.; Mackie, J.C.
Title:   The Pyrolysis of Cyclopentadiene: Quantum Chemical and Kinetic Modelling Studies of the Acetylene Plus Propyne/Allene Decomposition Channels
Journal:   Phys. Chem. Chem. Phys.
Volume:   3
Page(s):   2467 - 2473
Year:   2001
Reference type:   Journal article
Squib:   2001BAC/MAC2467-2473

Reaction:   CH2=C=CHCH=CH2C2H2 + CH3CCH
Reaction order:   1
Temperature:   1476 - 1618 K
Rate expression:   2.88x1013 [s-1] e-278445 [J/mole]/RT
Category:  Theory
Data type:   Ab initio
Pressure dependence:   Rate constant is high pressure limit

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1476 4.03E3
1500 5.80E3
1525 8.36E3
1550 1.19E4
1575 1.68E4
1600 2.34E4
1618 2.95E4