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Accessibility information
Author(s):   Trenwith, A.B.
Title:   Pyrolysis of propionitrile and the resonance stabilisation energy of the cyanomethyl radical
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   79
Year:   1983
Reference type:   Journal article
Squib:   1983TRE2755

Reaction:   C2H5CN·CH3 + CH2CN
Reaction order:   1
Temperature:   789 - 850 K
Pressure:  1.33E-2 - 0.13 bar
Rate expression:   3.16x1015 [s-1] e-329253 [±3293 J/mole]/RT
Uncertainty:   2.0
Bath gas:   C2H5CN
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
789 5.04E-7
800 1.00E-6
825 4.50E-6
850 1.85E-5