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Title: Photolysis of dimethyl carbonate
Journal: Trans. Faraday Soc.
Volume: 62
Page(s):
Year: 1966
Reference type: Journal article
Squib: 1966QUE/THY3154
Reaction:
CH3OCOOCH3 + CH3O· → CH3OH + CH3OC(O)OCH2·
Reaction order:
2
Reference reaction:
·CH3 + ·CH3 → C2H6
Temperature:
314 - 366
K
Rate expression:
9.33x10-14 [cm3/molecule s] e-24777 [J/mole]/RT
Bath gas:
CH3OCOOCH3
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 314 | 7.05E-18 |
| 325 | 9.72E-18 |
| 350 | 1.87E-17 |
| 366 | 2.72E-17 |