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Author(s):   Kroll, J.A.; Frandsen, B.N.; Rapf, R.J.; Kjaergaard, H.G.; Vaida, V.
Title:   Reactivity of Electronically Excited SO2 with Alkanes
Journal:   J. Phys. Chem. A
Volume:   122
Page(s):   7782 - 7789
Year:   2018
Reference type:   Journal article
Squib:   2018KRO/FRA7782-7789

Reaction:   3SO2 + iso-C4H10 → Products
Reaction order:   2
Temperature:   298 K
Pressure:  1.20E-2 bar
Rate expression:   6.0x10-13 [cm3/molecule s]
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)
Comments:   A computational potential energy surface study was also performed. It indicated that the reaction mechanism included formation of HOSO and an alkyl radical.

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