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 Author(s):   Weisshaar, J.C.
Title:   Reactions of gas phase transition metal atoms with small hydrocarbons
Page(s):   253 - 276
Year:   1992
Book Title:   Gas-Phase Metal Reactions
Publisher address:   ed. A. Fontijn, pub. Elsevier Science Publ., Amsterdam, Netherlands
Reference type:   Book Chapter
Squib:   1992WEI253-276C

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1992WEI253-276C   Cyclopropane + Ni → Products  300   1.00E-11              2
  1992WEI253-276C   Cyclopropane + Sc → Products  300   1.00E-14              2
  1992WEI253-276C   Cyclopropane + V → Products  300   2.01E-14              2
  1992WEI253-276C   1-C4H8 + Sc → Products  300   1.40E-11              2
  1992WEI253-276C   1-C4H8 + Ti → Products  300   7.11E-12              2
  1992WEI253-276C   1-C4H8 + V → Products  300   1.40E-11              2
  1992WEI253-276C   1,3-Butadiene + Ni → Products  300   1.10E-10              2
  1992WEI253-276C   1,3-Butadiene + Sc → Products  300   2.91E-11              2
  1992WEI253-276C   1,3-Butadiene + Ti → Products  300   1.00E-11              2
  1992WEI253-276C   1,3-Butadiene + Cr → Products  300   1.50E-13              2
  1992WEI253-276C   1,3-Butadiene + Co → Products  300   3.50E-13              2
  1992WEI253-276C   1,3-Butadiene + V → Products  300   1.50E-11              2
  1992WEI253-276C   CH3CH=CH2 + Sc → Products  300   9.51E-12              2
  1992WEI253-276C   CH3CH=CH2 + Ti → Products  300   6.19E-12              2
  1992WEI253-276C   CH3CH=CH2 + V → Products  300   9.60E-12              2
  1992WEI253-276C   Isobutene + Ni → Products  300   6.71E-11              2
  1992WEI253-276C   Isobutene + Sc → Products  300   7.11E-11              2
  1992WEI253-276C   Isobutene + Ti → Products  300   5.20E-11              2
  1992WEI253-276C   Isobutene + V → Products  300   6.79E-11              2
  1992WEI253-276C   CF3CF=CF2 + Ni → Products  300   3.01E-13              2
  1992WEI253-276C   (Z)-2-C4H8 + Ni → Products  300   1.55E-10              2
  1992WEI253-276C   (Z)-2-C4H8 + Sc → Products  300   3.30E-11              2
  1992WEI253-276C   (Z)-2-C4H8 + Ti → Products  300   1.40E-11              2
  1992WEI253-276C   (Z)-2-C4H8 + V → Products  300   3.01E-11              2
  1992WEI253-276C   (E)-2-C4H8 + Ni → Products  300   1.60E-10              2
  1992WEI253-276C   (E)-2-C4H8 + Sc → Products  300   2.01E-11              2
  1992WEI253-276C   (E)-2-C4H8 + Ti → Products  300   7.51E-12              2
  1992WEI253-276C   (E)-2-C4H8 + V → Products  300   2.19E-11              2
  1992WEI253-276C   CD3CD=CD2 + Sc → Products  300   8.30E-12              2
  1992WEI253-276C   CD3CD=CD2 + Ti → Products  300   5.00E-12              2
  1992WEI253-276C   CD3CD=CD2 + V → Products  300   9.60E-12              2
Search returned 31 records.