Kinetics Database Logo     Home
©NIST, 2022
Accessibility information
Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Contact Us to Submit an Article



Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

DOC home page

NIST home page

MML home page

Chemical Sciences Division

Applied Chemicals and Materials Division

Author(s):   Robaugh, D.; Tsang, W.
Title:   Thermal decomposition of phenyl iodide and o-iodotoluene
Journal:   J. Phys. Chem.
Volume:   90
Page(s):   5363 - 5367
Year:   1986
Reference type:   Journal article
Squib:   1986ROB/TSA5363-5367

Reaction:   IodobenzenePhenyl + I
Reaction order:   1
Reference reaction:   1,2-DimethylcyclohexeneC2H4 + CH2=C(CH3)C(CH3)=CH2
Temperature:   1050 - 1200 K
Pressure:  2.03 - 6.08 bar
Rate expression:   8.59x1014 [s-1] e-272715 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1050 2.33E1
1075 4.82E1
1100 9.64E1
1125 1.87E2
1150 3.53E2
1175 6.47E2
1200 1.16E3