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Author(s):   Burrows, J.P.; Moortgat, G.K.; Tyndall, G.S.; Cox, R.A.; Jenkin, M.E.; Hayman, G.D.; Veyret, B.
Title:   Kinetics and mechanism of the photooxidation of formaldehyde. 2. Molecular modulation studies
Journal:   J. Phys. Chem.
Volume:   93
Page(s):   2375 - 2382
Year:   1989
Reference type:   Journal article
Squib:   1989BUR/MOO2375-2382

Reaction:   HOCH2OO + HOCH2OO → Other Products + HCOOH
Reaction order:   2
Temperature:   298 K
Pressure:  0.93 bar
Rate expression:   5.6x10-13 [±2.82x10-13 cm3/molecule s]
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Sensitized photolysis
Analytical technique:   Fourier transform (FTIR)

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