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Accessibility information
Author(s):   Blades, A.T.
Title:   The kinetics of the pyrolysis of ethyl and isopropyl formates and acetates
Journal:   Can. J. Chem.
Volume:   32
Page(s):   366 - 372
Year:   1954
Reference type:   Journal article
Squib:   1954BLA366-372

Reaction:   HC(O)OC2H5HCOOH + C2H4
Reaction order:   1
Temperature:   810 - 920 K
Pressure:  1.96E-3 - 2.81E-3 bar
Rate expression:   2.13x1011 [s-1] e-184581 [±8314472 J/mole]/RT
Bath gas:   Toluene
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Other (direct)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
810 2.66E-1
825 4.38E-1
850 9.67E-1
875 2.04E0
900 4.13E0
920 7.06E0