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©NIST, 2013
Accessibility information
Author(s):   Balla, R.; Muthaiah, B.; Arathala, P.
Title:   Experimental and RRKM Investigations on the Degradation of Ethyl Formate
Journal:   ChemistrySelect
Volume:   2
Page(s):   11603 - 11614
Year:   2017
Reference type:   Journal article
Squib:   2017BAL/MUT11603-11614

Reaction:   HC(O)OC2H5HCOOH + C2H4
Reaction order:   1
Temperature:   909 - 1258 K
Pressure:  9.12 - 17.23 bar
Rate expression:   2.68x1011 [s-1] e-179494 [±9205 J/mole]/RT
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   None reported
Experimental procedure:   Shock tube
Excitation technique:   Thermal
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   Qualitative analyses of the post shock mixture were carried out using gas chromatography and FTIR.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
909 1.30E1
925 1.96E1
950 3.62E1
975 6.49E1
1000 1.13E2
1025 1.91E2
1050 3.16E2
1075 5.09E2
1100 8.03E2
1125 1.24E3
1150 1.89E3
1175 2.81E3
1200 4.12E3
1225 5.95E3
1250 8.47E3
1258 9.45E3