Author(s):   Dong, X.; Ninnemann, E.; Ranasinghe, D.S.; Laich, A.; Greene, R.; Vasu, S.S.; Green, W.H.
Title:   Revealing the critical role of radical-involved pathways in high temperature cyclopentanone pyrolysis
Journal:   Combust. Flame
Volume:   216
Page(s):   280 - 292
Year:   2020
Reference type:   Journal article
Squib:   2020DON/NIN280-292

Associated entries:

Search Results

Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |

Squib	Reaction	Temp [K]	A	n	Ea [J/mole]	Order
2020DON/NIN280-292	Cyclopentanone → ·CH₂CH₂CH₂CH₂C(=O)·	1156 - 1416	3.28E18	-3.50	3.57E05	1
2020DON/NIN280-292	·CH₂CH₂CH₂CH₂C(=O)· → ·CH₂CH₂CH₂CH₂· + CO	1156 - 1416	7.38E11	1.10	2.46E05	1
2020DON/NIN280-292	·CH₂CH₂CH₂CH₂· → C₂H₄ + C₂H₄	1156 - 1416	5.00E12			1
2020DON/NIN280-292	cyclopentanon-2-yl → ·CH₂CH₂CH₂CH=C=O	1156 - 1416	9.50E13		1.54E05	1
2020DON/NIN280-292	cyclopentanon-3-yl → CH₂=CHCH₂CH₂C(O)·	1156 - 1416	1.70E13		1.22E05	1
2020DON/NIN280-292	CH₂=CHCH₂CH₂C(O)· → CO + CH₂=CHCH₂CH₂·	1156 - 1416	6.10E14		6.53E04	1
2020DON/NIN280-292	·CH₂CH₂CH₂CH=C=O → C₂H₄ + CH₂=CHC(·)O	1156 - 1416	5.70E13		1.05E05	1

Search returned 7 records.