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Author(s):   Teruel, M.A.;Lane, S.I.;Mellouki, A.;Solignac, G.;Le Bras, G.
Title:   OH reaction rate constants and UV absorption cross-sections of unsaturated esters
Journal:   Atmos. Environ.
Volume:   40
Page(s):   3764 - 3772
Year:   2006
Reference type:   Journal article
Squib:   2006TER/LAN3764-3772

Reaction:   Methyl methacrylate + ·OH → Products
Reaction order:   2
Temperature:   253 - 374 K
Pressure:  1.01 bar
Rate expression:   2.5x10-12 [±8.0x10-13 cm3/molecule s] e6826 [±457 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
253 6.42E-11
275 4.95E-11
300 3.86E-11
325 3.13E-11
350 2.61E-11
374 2.25E-11