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Author(s):   Hickson, K.M.; Smith, I.W.M.
Title:   Rate Constants and Arrhenius Parameters for the Reactions of Cl Atoms with the Halogenated Ethers: CF3CH2OCHF2, CF3CHClOCHF2, and CF3CH2OCClF2
Journal:   Int. J. Chem. Kinet.
Volume:   33
Page(s):   165 - 172
Year:   2001
Reference type:   Journal article
Squib:   2001HIC/SMI165-172

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2001HIC/SMI165-172   CF3CH2OCHF2 + ·Cl → Products  295 - 363   5.15E-12       1.52E04   1.11E-14  2
  2001HIC/SMI165-172   ·Cl + CHF2OCHClCF3 → Products  295 - 363   1.60E-11       2.04E04   4.30E-15  2
  2001HIC/SMI165-172   CF3CH2OCClF2 + ·Cl → Products  295 - 363   9.60E-12       1.99E04   3.16E-15  2

Search returned 3 records.