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Accessibility information
Author(s):   Rembaum, A.; Szwarc, M.
Title:   O-O bond dissociation energies in propionyl and butyryl peroxides
Journal:   J. Chem. Phys.
Volume:   23
Page(s):   909 - 913
Year:   1955
Reference type:   Journal article
Squib:   1955REM/SZW909-913

Reaction:   CH3CH2C(O)O-OC(O)CH2CH3 → CH3CH2C(O)O· + CH3CH2C(O)O·
Reaction order:   1
Temperature:   373 - 464 K
Pressure:  1.01E-2 - 2.97E-2 bar
Rate expression:   2.5x1014 [s-1] e-125549 [±2511 J/mole]/RT
Bath gas:   Toluene
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
373 6.56E-4
375 8.13E-4
400 1.01E-2
425 9.28E-2
450 6.68E-1
464 1.84E0