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Author(s):   Kaiser, E.W.; Wallington, T.J.; Hurley, M.D.
Title:   Products and Mechanism of the Reaction of Cl with Butanone in N2/O2 Diluent at 297-526 K
Journal:   J. Phys. Chem. A
Volume:   113
Page(s):   2424 - 2437
Year:   2009
Reference type:   Journal article
Squib:   2009KAI/WAL2424-2437

Reaction:   C2H5COCH3 + ·ClHCl + CH3C(O)CH(·)CH3
Reaction order:   2
Temperature:   297 K
Pressure:  1.07 - 1.27 bar
Rate expression:   2.9x10-11 [±2.7x10-12 cm3/molecule s]
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   Gas chromatography and FTIR were used for product analysis. The error limit represents the relative precision based on the uncertainty in the product yields.

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