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Title: Kinetics and mechanism of reaction of difluorocarbene with molecular chlorine
Journal: Kinet. Catal.
Volume: 27
Page(s):
Year: 1986
Reference type: Journal article
Squib: 1986MEL/MOI17
Reaction:
·CF2 + Cl2 → CF2Cl2
Reaction order:
2
Reference reaction:
·CF2 + HCl → CHF2Cl
Reference reaction order:
2
Temperature:
433 - 523
K
Pressure: 1.01 bar
Rate expression:
5.01x10-4 e41822 [±8314472 J/mole]/RT
Uncertainty:
1.409999966621399
Bath gas:
HCl
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 433 | 5.56E1 |
| 450 | 3.58E1 |
| 475 | 1.99E1 |
| 500 | 1.17E1 |
| 523 | 7.53E0 |