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Author(s):   Mel'nikovich, S.V.; Moin, F.B.
Title:   Kinetics and mechanism of reaction of difluorocarbene with molecular chlorine
Journal:   Kinet. Catal.
Volume:   27
Year:   1986
Reference type:   Journal article
Squib:   1986MEL/MOI17

Reaction:   ·CF2 + Cl2CF2Cl2
Reaction order:   2
Reference reaction:   ·CF2 + HClCHF2Cl
Reference reaction order:   2
Temperature:   433 - 523 K
Pressure:  1.01 bar
Rate expression:   5.01x10-4 e41822 [±8314472 J/mole]/RT
Uncertainty:   1.409999966621399
Bath gas:   HCl
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
433 5.56E1
450 3.58E1
475 1.99E1
500 1.17E1
523 7.53E0