 |
Home ©NIST, 2023 Accessibility information |
Contact Us to Submit an Article
Other Databases
NIST Standard Reference Data Program
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
Administrative Links
Title: Reactions of CF2 carbene with Br2, Cl2 and H2 studied by means of CO2 laser photolysis and infrared diode laser spectroscopy
Journal: Chem. Phys. Lett.
Volume: 134
Page(s):
Year: 1987
Reference type: Journal article
Squib: 1987SUG/NAK347
Reaction:
·CF2 + Cl2 → CF2Cl2
Reaction order:
2
Temperature:
550
K
Pressure: 1.33E-4 - 5.33E-2 bar
Rate expression:
3.5x10-15 [±1.3x10-15 cm3/molecule s]
Bath gas:
Ar
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Flash photolysis (laser or conventional)
Analytical technique:
IR absorption
View full bibliographic record.