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Author(s):   Elsamra, R.MI.; Vranckx, S.; Carl, S.A.
Title:   CH(A2Δ) formation in hydrocarbon combustion: The temperature dependence of the rate constant of the reaction C2H+O2 -> CH(A2Δ)+CO2
Journal:   J. Phys. Chem. A
Volume:   109
Page(s):   10287 - 10293
Year:   2005
Reference type:   Journal article
Squib:   2005ELS/VRA10287-10293

Reaction:   ·C2H + → CH(A2Delta, B2Sigma-) + CO
Reaction order:   2
Reference reaction:   ·C2H + O2 → CH(A2Delta, B2Sigma-) + CO2
Reference reaction order:   2
Temperature:   295 K
Rate expression:   1.2x103±5.0x102
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Vis-UV emission
Comments:   195-nm photolysis of N2O and of SO2 used as source of O. C2H generated by photolysis of C2H2.

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