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Author(s):   Khaled, F.; Badra, J.; Faroooq, A.
Title:   A shock tube study of C4-C6 straight chain alkenes plus OH reactions
Journal:   Proc. Combust. Inst.
Volume:   36
Page(s):   289 - 298
Year:   2017
Reference type:   Journal article
Squib:   2017KHA/BAD289-298

Reaction:   ·OH + (Z)-2-C6H12 → Products
Reaction order:   2
Temperature:   891 - 1357 K
Pressure:  1.52 bar
Rate expression:   1.0x10-12 [±2.33x10-14 cm3/molecule s] (T/298 K)(2.17±0.37) e6113 [±230 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Shock tube
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Vis-UV absorption
Comments:   The experimentally measured OH profiles were fitted using a kinetic mechanism; sensitivity analysis demonstrated that the overall rate coefficient is insensitive to the details of the mechanism. The overall uncertainty is found to be ±15 - 20 % at 1100 K.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
891 2.46E-11
900 2.50E-11
925 2.59E-11
950 2.69E-11
975 2.79E-11
1000 2.89E-11
1025 3.00E-11
1050 3.10E-11
1075 3.21E-11
1100 3.33E-11
1125 3.44E-11
1150 3.56E-11
1175 3.68E-11
1200 3.80E-11
1225 3.92E-11
1250 4.05E-11
1275 4.18E-11
1300 4.31E-11
1325 4.45E-11
1350 4.58E-11
1357 4.62E-11