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Author(s):   Kaiser, E.W.;Donahue, C.J.;Pala, I.R.;Wallington, T.J.;Hurley, M.D.
Title:   Kinetics, products, and stereochemistry of the reaction of chlorine atoms with cis- and trans-2-butene in 10-700 torr of N2 or N2/O2 diluent at 297 k
Journal:   J. Phys. Chem. A
Volume:   111
Page(s):   1286 - 1299
Year:   2007
Reference type:   Journal article
Squib:   2007KAI/DON1286-1299

Reaction:   (E)-2-C4H8 + ·Cl → Products
Reaction order:   2
Reference reaction:   C3H8 + ·Cl → Products
Reference reaction order:   2
Temperature:   297 K
Pressure:  6.67E-2 bar
Rate expression:   2.03±2.0x10-1
Category:  Experiment
Data type:   Relative rate value measured
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography

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