Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Kaiser, E.W.;Donahue, C.J.;Pala, I.R.;Wallington, T.J.;Hurley, M.D.
Title:   Kinetics, products, and stereochemistry of the reaction of chlorine atoms with cis- and trans-2-butene in 10-700 torr of N2 or N2/O2 diluent at 297 k
Journal:   J. Phys. Chem. A
Volume:   111
Page(s):   1286 - 1299
Year:   2007
Reference type:   Journal article
Squib:   2007KAI/DON1286-1299

Reaction:   (E)-2-C4H8 + ·Cl → Products
Reaction order:   2
Temperature:   297 K
Pressure:  6.67E-2 bar
Rate expression:   2.9x10-10 [±3.0x10-11 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   Rate constant placed on absolute basis using k(Cl + C3H8 = 1.43 x 10-10 cm3s-1.

View full bibliographic record.