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Title: Kinetics, products, and stereochemistry of the reaction of chlorine atoms with cis- and trans-2-butene in 10-700 torr of N2 or N2/O2 diluent at 297 k
Journal: J. Phys. Chem. A
Volume: 111
Page(s): 1286 - 1299
Year: 2007
Reference type: Journal article
Squib: 2007KAI/DON1286-1299
Reaction:
(E)-2-C4H8 + ·Cl → Products
Reaction order:
2
Temperature:
297
K
Pressure: 6.67E-2 bar
Rate expression:
2.9x10-10 [±3.0x10-11 cm3/molecule s]
Category: Experiment
Data type:
Relative value normalized by a reference value
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Direct photolysis
Time resolution:
By end product analysis
Analytical technique:
Gas chromatography
Comments:
Rate constant placed on absolute basis using k(Cl + C3H8 = 1.43 x 10-10 cm3s-1.
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