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Title: An Exprimental and Computational Study on the CI Atom Initiated Photo-Oxidization Reactions of Butenes in the Gas Phase
Journal: J. Phys. Chem. A
Volume: 121
Page(s): 5487 - 5499
Year: 2017
Reference type: Journal article
Squib: 2017VIJ/RAJ5487-5499
Reaction:
(E)-2-C4H8 + ·Cl → Products
Reaction order:
2
Temperature:
269 - 363
K
Pressure: 0.93 bar
Rate expression:
1.11x10-10 [±3.0x10-11 cm3/molecule s] e2420 [±732 J/mole]/RT
Category: Experiment
Data type:
Relative value normalized by a reference value
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Direct photolysis
Time resolution:
By end product analysis
Analytical technique:
Gas chromatography
Comments:
1,3-Butadiene, isoprene, and 1-pentene were used as reference compounds.
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 269 | 3.27E-10 |
| 275 | 3.20E-10 |
| 300 | 2.93E-10 |
| 325 | 2.72E-10 |
| 350 | 2.55E-10 |
| 363 | 2.47E-10 |