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Title: Catalysis by hydrogen halides in the gas phase
Journal: Chem. Ind. (London)
Page(s): 207 - 208
Year: 1961
Reference type: Journal article
Squib: 1961STI/WAT207-208
Reaction:
tert-C4H9OCH3 → CH3OH + iso-C4H8
Reaction order:
2
Temperature:
531 - 644
K
Pressure: 0.20 - 0.89 bar
Rate expression:
1.11x10-12 [cm3/molecule s] e-107257 [J/mole]/RT
Bath gas:
HBr
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Pressure measurement
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 531 | 3.13E-23 |
| 550 | 7.25E-23 |
| 575 | 2.01E-22 |
| 600 | 5.12E-22 |
| 625 | 1.21E-21 |
| 644 | 2.22E-21 |