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Title: Pyrolysis of methyl tert-butyl ether
Journal: Oxid. Commun.
Volume: 1
Page(s):
Year: 1980
Reference type: Journal article
Squib: 1980BRO/BAR321
Reaction:
tert-C4H9OCH3 → CH3OH + iso-C4H8
Reaction order:
1
Temperature:
623 - 763
K
Pressure: 6.67E-2 - 0.27 bar
Rate expression:
1.0x1014 [s-1] e-249434 [J/mole]/RT
Bath gas:
tert-C4H9OCH3
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 623 | 1.22E-7 |
| 625 | 1.43E-7 |
| 650 | 9.03E-7 |
| 675 | 4.99E-6 |
| 700 | 2.44E-5 |
| 725 | 1.07E-4 |
| 750 | 4.25E-4 |
| 763 | 8.40E-4 |