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Author(s):   Lifshitz, A.; Tamburu, C.; Dubnikova, F.
Title:   Reactions of 1-naphthyl radicals with ethylene. Single pulse shock tube experiments, quantum chemical, transition state theory, and multiwell calculations
Journal:   J. Phys. Chem. A
Volume:   112
Page(s):   925 - 933
Year:   2008
Reference type:   Journal article
Squib:   2008LIF/TAM925-933

Reaction:   Acenaphthene + C2H3 → C12H9 + C2H4
Reaction order:   2
Temperature:   950 - 1200 K
Pressure:  1.87 - 2.47 bar
Rate expression:   4.98x10-11 [cm3/molecule s] e-33472 [J/mole]/RT
Category:  Experiment
Data type:   Estimated: thermochemical, kinetic, or other
Experimental procedure:   Shock tube
Time resolution:   In real time
Analytical technique:   GC-MS

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
950 7.19E-13
975 8.02E-13
1000 8.89E-13
1025 9.81E-13
1050 1.08E-12
1075 1.18E-12
1100 1.28E-12
1125 1.39E-12
1150 1.50E-12
1175 1.62E-12
1200 1.74E-12