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Author(s):   Anderson, H.R., Jr.; Scheraga, H.A.; VanArtsdalen, E.R.
Title:   Bromination of hydrocarbons. VI. Photochemical and thermal bromination of toluene. Bond dissociation energies
Journal:   J. Chem. Phys.
Volume:   21
Page(s):  
Year:   1953
Reference type:   Journal article
Squib:   1953AND/SCH1258

Reaction:   Toluene + Br· → Benzyl + HBr
Reaction order:   2
Temperature:   435 - 445 K
Pressure:  0.16 - 0.20 bar
Rate expression:   5.48x10-11 [cm3/molecule s] e-30098 [J/mole]/RT
Bath gas:   Toluene
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   IR absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
435 1.33E-14
445 1.61E-14