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Title: Pyrolysis of tertiarybutylphosphine
Journal: J. Electron. Mater.
Volume: 18
Page(s): 457 - 462
Year: 1989
Reference type: Journal article
Squib: 1989LI/LAR457-462
Reaction:
tert-C4H9 + tert-C4H9PH2 → (CH3)3CPH + iso-C4H10
Reaction order:
2
Temperature:
648 - 723
K
Pressure: 1.01 bar
Rate expression:
1.05x10-12 [cm3/molecule s] e-72086 [J/mole]/RT
Bath gas:
D2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 648 | 1.62E-18 |
| 650 | 1.69E-18 |
| 675 | 2.77E-18 |
| 700 | 4.38E-18 |
| 723 | 6.49E-18 |