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Accessibility information
Author(s):   Brown, T.C.; King, K.D.
Title:   Very low-pressure pyrolysis (VLPP) of methyl- and ethynyl- cyclopentanes and cyclohexanes
Journal:   Int. J. Chem. Kinet.
Volume:   21
Page(s):   251 - 266
Year:   1989
Reference type:   Journal article
Squib:   1989BRO/KIN251-266

Reaction:   Methylcyclohexane1-C7H14 + 2-C7H14
Reaction order:   1
Temperature:   1010 - 1210 K
Rate expression:   2.51x1016 [s-1] e-345051 [±10310 J/mole]/RT
Uncertainty:   2.0
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1010 3.59E-2
1025 6.55E-2
1050 1.72E-1
1075 4.30E-1
1100 1.03E0
1125 2.39E0
1150 5.34E0
1175 1.15E1
1200 2.40E1
1210 3.19E1