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Accessibility information
Author(s):   Birrell, R.N.; Trotman-Dickenson, A.F.
Title:   The reactions of alkyl radicals. Part VI. The reactions of methyl radicals with aliphatic aldehydes
Journal:   J. Chem. Soc.
Page(s):  
Year:   1960
Reference type:   Journal article
Squib:   1960BIR/TRO2059

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1960BIR/TRO2059   CH3CHO + ·CH3CH4 + CH3CO  395 - 447   1.32E-12       3.18E04      2
  1960BIR/TRO2059   (CH3)2CHCHO + ·CH3CH4 + (CH3)2CHC=O  395 - 448   6.61E-12       3.64E04      2
  1960BIR/TRO2059   sec-C4H9CHO + ·CH3 → Other Products + CH4  385 - 436   2.09E-11       4.35E04      2
  1960BIR/TRO2059   Pentanal + ·CH3CH4 + CH3CH2CH2CH2CO·  394 - 447   2.09E-12       3.34E04      2
  1960BIR/TRO2059   CH3CH2CH2CHO + ·CH3CH4 + CH3CH2CH2CO  394 - 447   1.05E-12       3.05E04      2
  1960BIR/TRO2059   3-Methylbutanal + ·CH3CH4 + iso-C4H9CO·  399 - 444   3.32E-12       3.52E04      2
  1960BIR/TRO2059   2,2-dimethylpropanal + ·CH3CH4 + (CH3)3CC(O)·  392 - 436   1.66E-11       4.27E04      2
  1960BIR/TRO2059   ·CH3 + (E)-CH3CH=CHCHOCH4 + CH3CH=CHC(O)·  394 - 448   3.32E-11       4.56E04      2

Search returned 8 records.