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Accessibility information
Author(s):   Birrell, R.N.; Trotman-Dickenson, A.F.
Title:   The reactions of alkyl radicals. Part VI. The reactions of methyl radicals with aliphatic aldehydes
Journal:   J. Chem. Soc.
Year:   1960
Reference type:   Journal article
Squib:   1960BIR/TRO2059

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1960BIR/TRO2059   CH3CHO + ·CH3CH4 + CH3CO  395 - 447   1.32E-12       3.18E04      2
  1960BIR/TRO2059   (CH3)2CHCHO + ·CH3CH4 + (CH3)2CHC=O  395 - 448   6.61E-12       3.64E04      2
  1960BIR/TRO2059   sec-C4H9CHO + ·CH3 → Other Products + CH4  385 - 436   2.09E-11       4.35E04      2
  1960BIR/TRO2059   Pentanal + ·CH3CH4 + CH3CH2CH2CH2CO·  394 - 447   2.09E-12       3.34E04      2
  1960BIR/TRO2059   CH3CH2CH2CHO + ·CH3CH4 + CH3CH2CH2CO  394 - 447   1.05E-12       3.05E04      2
  1960BIR/TRO2059   3-Methylbutanal + ·CH3CH4 + iso-C4H9CO·  399 - 444   3.32E-12       3.52E04      2
  1960BIR/TRO2059   2,2-dimethylpropanal + ·CH3CH4 + (CH3)3CC(O)·  392 - 436   1.66E-11       4.27E04      2
  1960BIR/TRO2059   ·CH3 + (E)-CH3CH=CHCHOCH4 + CH3CH=CHC(O)·  394 - 448   3.32E-11       4.56E04      2

Search returned 8 records.