Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2020
Accessibility information
Author(s):   Tschuikow-Roux, E.; Yano, T.; Niedzielski, J.
Title:   Photochlorination of chloroethane and chloroethane-d5
Journal:   J. Phys. Chem.
Volume:   88
Page(s):   1408 - 1414
Year:   1984
Reference type:   Journal article
Squib:   1984TSC/YAN1408-1414

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1984TSC/YAN1408-1414   C2H5Cl + ·ClHCl + CH2CH2Cl  281 - 367   1.35E-11       7242   7.26E-13  2
  1984TSC/YAN1408-1414   C2H5Cl + ·ClHCl + CH3CHCl  281 - 367   1.43E-11       3841   3.03E-12  2
  1984TSC/YAN1408-1414   C2H5Cl + ·ClHCl + CH3CHCl  281 - 367   0.87       -8896   31.51  2
  Reference reaction:  CH4 + ·Cl·CH3 + HCl 2
  1984TSC/YAN1408-1414   C2H5Cl + ·ClHCl + CH3CHCl  280 - 368   1.06       3401   0.27  2
  Reference reaction:  C2H5Cl + ·ClHCl + CH2CH2Cl 2
  1984TSC/YAN1408-1414   C2D5Cl + ·Cl → CD3CD(·)Cl + DCl  281 - 367   7.21E-12       3891   1.50E-12  2
  1984TSC/YAN1408-1414   C2D5Cl + ·Cl → CD3CD(·)Cl + DCl  281 - 367   0.44       -8813   15.29  2
  Reference reaction:  CH4 + ·Cl·CH3 + HCl 2
  1984TSC/YAN1408-1414   C2D5Cl + ·Cl → CD3CD(·)Cl + DCl  280 - 368   1.21       5720   0.12  2
  Reference reaction:  C2D5Cl + ·Cl → ·CD2CD2Cl + DCl 2
  1984TSC/YAN1408-1414   C2D5Cl + ·Cl → ·CD2CD2Cl + DCl  281 - 367   5.99E-12       9645   1.22E-13  2

Search returned 8 records.