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Title: Correlations between rate parameters and calculated molecular properties in the reactions of the nitrate radical with alkenes
Journal: J. Chem. Soc. Faraday Trans.
Volume: 89
Page(s): 3899 - 3905
Year: 1993
Reference type: Journal article
Squib: 1993MAR/MON3899-3905
Reaction:
(CH3)2C=CHCH3 + NO3 → Products
Reaction order:
2
Temperature:
270 - 330
K
Rate expression:
1.4x10-13 [cm3/molecule s] e9229 [J/mole]/RT
Category: Theory
Data type:
Other theoretical
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 270 | 8.54E-12 |
| 275 | 7.93E-12 |
| 300 | 5.66E-12 |
| 325 | 4.26E-12 |
| 330 | 4.04E-12 |