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Author(s):   Ramacher, B.; Orlando, J.J.; Tyndall, G.S.
Title:   Temperature-Dependent Rate Coefficient Measurements for the Reaction of Bromine Atoms with a Series of Aldehydes
Journal:   Int J. Chem. Kinet.
Volume:   2000
Page(s):   460 - 465
Year:   2000
Reference type:   Journal article
Squib:   2000RAM/ORL460-465

Reaction:   CH3CH2CH2CHO + Br·HBr + CH3CH2CH2CO
Reaction order:   2
Reference reaction:   CH2O + Br·HCO + HBr
Reference reaction order:   2
Temperature:   250 - 296 K
Pressure:  0.93 bar
Rate expression:   8.62±6.9x10-1
Bath gas:   N2
Category:  Experiment
Data type:   Relative rate value measured
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Fourier transform (FTIR)
Comments:   Photolysis of Br2 in absence of O2.Relative rate constant independent of temperature.

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