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Author(s):   Kurylo, M.J.; Knable, G.L.
Title:   A kinetics investigation of the gas-phase reactions of Cl(2P) and OH(X2II) with CH3CN: Atmospheric significance and evidence for decreased reactivity between strong electrophiles
Journal:   J. Phys. Chem.
Volume:   88
Page(s):   3305 - 3308
Year:   1984
Reference type:   Journal article
Squib:   1984KUR/KNA3305-3308

Reaction:   CH3CN + ·OHCH2CN + H2O
Reaction order:   2
Temperature:   250 - 363 K
Pressure:  2.67E-2 - 6.67E-2 bar
Rate expression:   6.28x10-13 [cm3/molecule s] e-8564 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Resonance fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
250 1.02E-14
275 1.48E-14
300 2.03E-14
325 2.64E-14
350 3.31E-14
363 3.68E-14