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Title: Gas phase kinetics of pyrolysis of 1-methyl-1-cyclopropene
Journal: Chem. Ber.
Volume: 118
Page(s):
Year: 1985
Reference type: Journal article
Squib: 1985HOP/WAC3579
Reaction:
1-methylcyclopropene → 1,2-butadiene
Reaction order:
1
Temperature:
483 - 523
K
Pressure: 5.33E-3 - 0.33 bar
Rate expression:
3.09x1013 [s-1] e-182918 [±5488 J/mole]/RT
Uncertainty:
5.0
Bath gas:
SF6
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 483 | 5.11E-7 |
| 500 | 2.40E-6 |
| 523 | 1.66E-5 |