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Author(s):   Bell, T.N.; Slade, P.; Sherwood, A.G.
Title:   Kinetics of the abstraction of H from group IV methyls by CF3 and CD3 radicals
Journal:   Can. J. Chem.
Volume:   52
Page(s):   1662 - 1667
Year:   1974
Reference type:   Journal article
Squib:   1974BEL/SLA1662-1667

Reaction:   (CH3)4Sn + CD3CHD3 + (CH3)3SnCH2·
Reaction order:   2
Reference reaction:   CD3 + CD3C2D6
Temperature:   298 - 423 K
Pressure:  6.67E-2 bar
Rate expression:   2.41x10-12 [cm3/molecule s] e-47226 [±948 J/mole]/RT
Uncertainty:   1.25999999
Bath gas:   (CH3)4Sn
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 1.27E-20
300 1.44E-20
325 6.19E-20
350 2.16E-19
375 6.36E-19
400 1.64E-18
423 3.55E-18