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Author(s):   Cadman, P.; Tilsley, G.M.; Trotman-Dickenson, A.F.
Title:   Reactions of trichlorosilyl radicals with n-propyl chloride, cyclopentyl chloride, and carbon tetrachloride
Journal:   J. Chem. Soc. A
Page(s):   1370 - 1372
Year:   1969
Reference type:   Journal article
Squib:   1969CAD/TIL1370-1372

Reaction:   Cyclopentane, chloro- + SiCl3Cyclopentyl + SiCl4
Reaction order:   2
Reference reaction:   CH3Cl + SiCl3·CH3 + SiCl4
Reference reaction order:   2
Temperature:   353 - 443 K
Rate expression:   5.2x10-1 e10643 [J/mole]/RT
Bath gas:   SiHCl3
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
353 1.95E1
375 1.58E1
400 1.28E1
425 1.06E1
443 9.35E0